Yan Wenjuan, Zhang Guangyu, Wang Jinyao, Liu Mengyuan, Sun Yu, Zhou Ziqi, Zhang Wenxiang, Zhang Shuxia, Xu Xiaoqiang, Shen Jian, Jin Xin
State Key Laboratory of Heavy Oil Processing, Center for Chemical Engineering Experimental Teaching, China University of Petroleum, Qingdao, China.
Oil Production Group#2, Huabei Oil Field Company at PetroChina, Langfang, China.
Front Chem. 2020 Mar 31;8:185. doi: 10.3389/fchem.2020.00185. eCollection 2020.
Adipic acid is one of the most important feedstocks for producing resins, nylons, lubricants, plasticizers. Current industrial petrochemical process, producing adipic acid from KA oil, catalyzed by nitric acid, has a serious pollution to the environment, due to the formation of waste nitrous oxide. Hence, developing cleaner methods to produce adipic acid has attracted much attention of both industry and academia. This mini-review article discussed advances on adipic acid synthesis from bio-renewable feedstocks, as well as most recent progress on cleaner technology from fossil fuels over novel catalytic materials. This work on recent advances in green adipic acid production will provide insights and guidance to further study of various other industrial processes for producing nylon precursors.
己二酸是生产树脂、尼龙、润滑剂、增塑剂最重要的原料之一。目前由KA油经硝酸催化生产己二酸的工业石化工艺,由于会产生一氧化二氮废物,对环境造成严重污染。因此,开发更清洁的己二酸生产方法已引起工业界和学术界的广泛关注。这篇综述文章讨论了从生物可再生原料合成己二酸的进展,以及通过新型催化材料从化石燃料中获取更清洁技术的最新进展。这项关于绿色己二酸生产最新进展的工作将为进一步研究生产尼龙前体的各种其他工业工艺提供见解和指导。