Synthesis of a novel 3,5-diacrylamidobenzoic acid based hyper-cross-linked resin for the efficient adsorption of Congo Red and Rhodamine B.

A novel hyper cross-linked, 3,5-diacrylamidobenzoic acid based resin (APEADA) has been synthesized for the highly efficient removal of Congo red (CR) and Rhodamine B (RhB) from aqueous solution. The synthesized resin was extensively characterized by FT-IR, FESEM, PXRD, EDX, BET analysis, TGA and solid state C (CP-MAS) NMR. APEADA exhibits thermal stability (≈ 200 °C) and a considerable surface area (64.78 m g), as suggested by Thermogravimetric Analysis (TGA) and Brunauer-Emmett-Teller (BET) analysis, respectively. The experimental data of dyes adsorption onto resin was examined by a variety of isotherm models wherein Langmuir and Temkin models were found to be the best fit for explaining the adsorption of both RhB (R = 0.9899) and CR (R = 0.9919). The resin can efficiently remove CR (92.03%) at pH 8.14 and moderately adsorb RhB (45.3%) at pH 5.01 and exhibits maximum adsorption capacity (Q) for CR (280.0 mg g) and RhB (23.28 mg g) at 318.6 K. The thermodynamic analysis of the data revealed that the adsorption processes were exothermic and spontaneous. Moreover, APEADA showed efficient removal efficiency (80.13%) for dyes in simulated effluents which warrants its utility and effectiveness in industrial waste water treatment.