Shchukina E, Shchukin D G
Stephenson Institute for Renewable Energy, Department of Chemistry , University of Liverpool , Crown Street , L69 7ZD Liverpool , U.K.
Langmuir. 2019 Jul 2;35(26):8603-8611. doi: 10.1021/acs.langmuir.9b00151. Epub 2019 Feb 27.
We highlight the development of nanocontainer-based active materials started in 2006 at the Max Planck Institute of Colloids and Interfaces under the supervision of Prof. Helmuth Möhwald. The active materials encapsulated in the nanocontainers with controlled shell permeability have been first applied for self-healing coatings with controlled release of the corrosion inhibitor. The nanocontainers have been added to the paint formulation matrix at 5-10 wt % concentration, which resulted in attaining a coating-autonomous self-healing ability. This research idea has attracted the attention of many scientists around the world (>1500 publications during the last 10 years) and has already been transferred to the commercialization level. The current trend in nanocontainer-based active systems is devoted to the multifunctionality of the capsules which can combine self-healing, antibacterial, thermal, and other functionalities into one host matrix. This article summarizes the previous research done in the area of nanocontainer-based active materials together with future perspectives of capsule-based materials with antifouling or thermoregulating activity.
我们着重介绍了基于纳米容器的活性材料的发展历程，该研究始于2006年，由马克斯·普朗克胶体与界面研究所的赫尔穆特·默瓦尔德教授监督。封装在具有可控壳渗透性的纳米容器中的活性材料首次应用于具有缓蚀剂控释功能的自修复涂层。纳米容器以5-10 wt%的浓度添加到涂料配方基质中，从而实现了涂层自主自修复能力。这一研究思路引起了全球众多科学家的关注（过去10年中有超过1500篇相关出版物），并且已经进入商业化阶段。基于纳米容器的活性系统当前的发展趋势致力于胶囊的多功能性，即将自修复、抗菌、热及其他功能整合到一个主体基质中。本文总结了此前在基于纳米容器的活性材料领域所开展的研究，以及具有防污或温度调节活性的胶囊基材料的未来前景。
