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对辐射松木材的化学分级评估:结构成分衍生产物的特性研究。

Assesment on the chemical fractionation of Eucalyptus nitens wood: Characterization of the products derived from the structural components.

机构信息

Chemical Engineering Department, University of Vigo (Campus Ourense), Polytechnical Building, As Lagoas, 32004 Ourense, Spain.

Instituto de Recursos Naturales y Agrobiología de Sevilla (IRNAS), CSIC, PO Box 1052, E-41080 Seville, Spain.

出版信息

Bioresour Technol. 2019 Jun;281:269-276. doi: 10.1016/j.biortech.2019.02.098. Epub 2019 Feb 22.

Abstract

Following an integrated approach, Eucalyptus nitens wood samples were subjected to consecutive stages of aqueous fractionation and organosolv delignification, in order to separate hemicelluloses (mainly converted into soluble products from the aqueous stage) from lignin (largely converted into soluble fragments in the organosolv stage) and from cellulose (accumulated in the solid phase from pulping). The compositions of selected reaction media were studied by selected spectrophotometric, spectrometric, chromatographic, and nuclear magnetic resonance methods; and the solid phases from treatments were studied by diffractometry and scanning electron microscopy. The experimental information from the above tasks provides a deep insight on the yields, properties and potential applications of the target fractions in the scope of biorefineries.

摘要

桉树木材样本采用综合方法,经过连续的水相分级和有机溶剂脱木质素处理,以将半纤维素(主要从水相转化为可溶性产物)、木质素(主要从有机溶剂相转化为可溶性片段)和纤维素(从纸浆中积累在固相)分离。通过选择分光光度法、光谱法、色谱法和核磁共振法研究了所选反应介质的组成;通过衍射法和扫描电子显微镜研究了处理后的固相。上述任务的实验信息深入了解了目标馏分在生物精炼厂范围内的产率、性质和潜在应用。

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