Magnetic mesoporous nanoparticles modified with poly(ionic liquids) with multi-functional groups for enrichment and determination of pyrethroid residues in apples.

Considering that the determination of pyrethroid residues is of value for the safety of food, a new poly(ionic liquid)-functionalized magnetic mesoporous nanoparticle was designed and used as an adsorbent in magnetic solid-phase extraction for the enrichment of eight pyrethroids. The porous structure and large surface area of the mesoporous silica shell endow the adsorbent with abundant binding sites. In contrast to the reported poly(ionic liquids) with only one kind of functional group in the cationic part, the new poly(ionic liquids) with mixed cyano and phenyl groups in cationic part matched the chemical structure of the analytes to improve extraction efficiency. Under the optimum conditions, an effective method was established for the determination of eight pyrethroids in apples. Adsorption equilibrium can be quickly reached in 1 min, greatly decreasing the extraction time. The linearity range was found to be 10-200 ng/g, and the detection limits ranged from 0.24 to 1.99 ng/g. Recoveries of analytes in apple samples ranged from 87.3 to 119.0%, with relative standard deviations varying in the range of 3-21.2% (intraday) and 0.3-15.2% (interday). The results indicate that the proposed method is a good candidate for pyrethroid residues in apple samples.