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负载银的稻壳气化炭对模拟烟气中汞的脱除

Removal of Hg from simulated flue gas over silver-loaded rice husk gasification char.

作者信息

Yang Ru, Diao Yongfa, Abayneh Befkadu

机构信息

College of Environmental Science and Engineering, Donghua University, Shanghai 201620, People's Republic of China.

College of Energy and Architectural engineering, Henan University of Urba Construction, Pingdingshan 467001, People's Republic of China.

出版信息

R Soc Open Sci. 2018 Sep 12;5(9):180248. doi: 10.1098/rsos.180248. eCollection 2018 Sep.

Abstract

Mercury released into the atmosphere from coal combustion is harmful to humans and the environment. Rice husk gasification char (RHGC) is an industrial waste of biomass gasification power generation, which is silver-loaded to develop a novel and efficient sorbent for mercury removal from simulated flue gas. The experiment was carried out in a fixed-bed experimental system. The Hg adsorption performance of RHGC was improved significantly after loading silver. Hg adsorption capacity and mercury inlet concentration were found to be nonlinear. The adsorption capacity of RHGC decreased with the increase of reaction temperature. SO inhibited mercury removal, NO and HCl promoted mercury removal; the Hg adsorption capacity in the simulated flue gas was higher than that in pure N. The silver-loaded rice husk gasification char (SRHGC) could be recycled about five times without significantly losing its removal efficiency. The SRHGC will not only reduce the cost of mercury removal but also save energy and reduce environmental pollution. At the same time, it provides a new way for the resource utilization of RHGC.

摘要

煤炭燃烧释放到大气中的汞对人类和环境有害。稻壳气化炭(RHGC)是生物质气化发电的工业废弃物,通过负载银来开发一种新型高效吸附剂,用于从模拟烟气中脱汞。实验在固定床实验系统中进行。负载银后,RHGC的汞吸附性能显著提高。发现汞吸附容量与汞入口浓度呈非线性关系。RHGC的吸附容量随反应温度的升高而降低。SO抑制汞的脱除,NO和HCl促进汞的脱除;模拟烟气中的汞吸附容量高于纯N中的汞吸附容量。负载银的稻壳气化炭(SRHGC)可循环使用约五次,且其脱除效率不会显著降低。SRHGC不仅能降低脱汞成本,还能节约能源和减少环境污染。同时,它为RHGC的资源利用提供了一条新途径。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/681d/6170578/36142e569080/rsos180248-g1.jpg

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