Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, National Demonstration Center for Experimental Chemistry Education, College of Chemistry & Materials Science , Northwest University , Xi'an 710069 , P. R. China.
College of Chemistry & Pharmacy , Northwest A&F University , Yangling 712100 , P. R. China.
Inorg Chem. 2019 Mar 18;58(6):4019-4025. doi: 10.1021/acs.inorgchem.9b00113. Epub 2019 Mar 6.
An interpenetrated indium pyridylcarboxylate framework, [NH(CH)][In(L)]·2.5DMF·5HO (1), has been synthesized by employing a pyridylcarboxylate ligand, 4-(3-carboxylphenyl)picolinic acid (HL), and an In ion, with both chemical stability and framework flexibility. The desolvated 1 exhibits an uncommon breathing sorption behavior and shows highly selective adsorption for CH, CH, and CO over CH. Furthermore, 1 shows rapid and higher adsorption efficiency for methylene blue and neutral red in aqueous solution.
一种互穿的铟吡啶羧酸骨架化合物，[NH(CH)][In(L)]·2.5DMF·5H2O（1），通过使用吡啶羧酸配体，4-(3-羧基苯基)吡啶酸（HL）和铟离子，具有化学稳定性和骨架灵活性。脱溶剂的 1 表现出一种不常见的呼吸吸附行为，并对 CH、CH 和 CO 表现出高度选择性的吸附，而对 CH 则没有。此外，1 对水中的亚甲基蓝和中性红表现出快速和更高的吸附效率。
