铜、镍和钴的 N-杂环卡宾配合物。
N-Heterocyclic Carbene Complexes of Copper, Nickel, and Cobalt.
机构信息
Laboratory of Inorganic Chemistry , National and Kapodistrian University of Athens , Panepistimiopolis Zografou , Athens GR 15771 , Greece.
Université de Strasbourg, CNRS, Institut de Chimie UMR 7177 , Laboratoire de Chimie de Coordination , Strasbourg 67081 Cedex , France.
出版信息
Chem Rev. 2019 Mar 27;119(6):3730-3961. doi: 10.1021/acs.chemrev.8b00505. Epub 2019 Mar 7.
The emergence of N-heterocyclic carbenes as ligands across the Periodic Table had an impact on various aspects of the coordination, organometallic, and catalytic chemistry of the 3d metals, including Cu, Ni, and Co, both from the fundamental viewpoint but also in applications, including catalysis, photophysics, bioorganometallic chemistry, materials, etc. In this review, the emergence, development, and state of the art in these three areas are described in detail.
作为配体的 N-杂环卡宾在整个元素周期表中的出现，对包括 Cu、Ni 和 Co 在内的 3d 金属的配位、有机金属和催化化学的各个方面都产生了影响，无论是从基础观点还是应用角度来看，包括催化、光物理、生物有机金属化学、材料等方面。在这篇综述中，详细描述了这三个领域的出现、发展和最新进展。
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