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采用YSZ/ZTA涂层改善固体/气体复合绝缘的介电性能

Improvement of dielectric performance of solid/gas composite insulation with YSZ/ZTA coatings.

作者信息

Sun Zhu, Fan Weiwei, Liu Zhiyuan, Bai Yu, Geng Yingsan, Wang Jianhua

机构信息

State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Xi'an, 710049, People's Republic of China.

Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, 02139, USA.

出版信息

Sci Rep. 2019 Mar 7;9(1):3888. doi: 10.1038/s41598-019-40515-8.

Abstract

N has been introduced to gas-insulated switchgears (GIS) as an environmentally friendly insulation medium for SF gas. Considering the low breakdown strength of N, it's essential to apply a dielectric coating on part of the electrode in GIS. In the current work, yttria-stabilized zirconia (YSZ) and zirconia-toughened alumina (ZTA) ceramics are tactfully applied as dielectric coating materials and successfully coated on the surface of rod electrode via high efficiency supersonic atmospheric plasma spraying method. It is demonstrated that both YSZ and ZTA have excellent thermal stability. In the measured frequency range 10-10 Hz, the dielectric constant (ε') decreases with the increase in frequency. At measured temperatures (0-140 °C), ε' increases from 15.45 to 16.31 for YSZ ceramic at 1 kHz, while it varies between 30.23 and 39.34 for ZTA ceramic. As compared to that of bare electrode, the 50% BDV (U) of solid/gas composite insulation system is significantly improved when using YSZ and ZTA as coating materials. Furthermore, the U increases with the increase of coating thickness. For the electrode coated with ZTA ceramic (500 μm), the U value reaches to 86 kV, which is enhanced about 21.13% in comparison with that of bare electrode. With respect to YSZ ceramic coating (500 μm), a higher U value of 88 kV is obtained. This is mainly due to that YSZ has a lower permittivity, which can generate a more uniform electric field distribution between the rod and plane electrodes, bringing about a higher breakdown voltage.

摘要

氮气已作为一种环保的绝缘介质被引入气体绝缘开关设备(GIS)中,以替代六氟化硫气体。考虑到氮气的击穿强度较低,在GIS的部分电极上施加介电涂层至关重要。在当前工作中,巧妙地将氧化钇稳定的氧化锆(YSZ)和氧化锆增韧氧化铝(ZTA)陶瓷用作介电涂层材料,并通过高效超音速大气等离子喷涂方法成功涂覆在棒状电极表面。结果表明,YSZ和ZTA都具有出色的热稳定性。在10-10赫兹的测量频率范围内,介电常数(ε')随频率增加而降低。在测量温度(0-140°C)下,对于YSZ陶瓷,在1千赫兹时ε'从15.45增加到16.31,而对于ZTA陶瓷,其值在30.23至39.34之间变化。与裸电极相比,当使用YSZ和ZTA作为涂层材料时,固体/气体复合绝缘系统的50%击穿电压(U)显著提高。此外,U随涂层厚度的增加而增加。对于涂覆有ZTA陶瓷(500微米)的电极,U值达到86千伏,与裸电极相比提高了约21.13%。对于YSZ陶瓷涂层(500微米),获得了更高的U值88千伏。这主要是因为YSZ的介电常数较低,这可以在棒状电极和平板电极之间产生更均匀的电场分布,从而带来更高的击穿电压。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/136a/6405924/a98c09780989/41598_2019_40515_Fig1_HTML.jpg

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