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同核自适应动力学极化转移(Homonuclear ADAPT):一种获得长寿命核单重态序的通用制备途径。

Homonuclear ADAPT: A general preparation route to long-lived nuclear singlet order.

作者信息

Elliott Stuart J, Stevanato Gabriele

机构信息

School of Chemistry, University of Southampton, Southampton SO17 1BJ, United Kingdom.

Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), Batochime, CH-1015 Lausanne, Switzerland.

出版信息

J Magn Reson. 2019 Apr;301:49-55. doi: 10.1016/j.jmr.2019.02.005. Epub 2019 Mar 4.

Abstract

We introduce a simple strategy to access and readout nuclear singlet order based on the alternate repetition of hard pulses and delays. We demonstrate the general applicability of the method by accessing nuclear singlet order in spin systems characterized by diverse coupling regimes. We show that the method is highly efficient in the strong-coupling and chemical equivalence regimes, and can overcome some limitations of other well-established and more elaborated pulse sequences. A simulation package is provided which allows the determination of pulse sequence parameters.

摘要

我们介绍了一种基于硬脉冲和延迟的交替重复来获取和读出核单重态序的简单策略。我们通过在具有不同耦合机制的自旋系统中获取核单重态序,证明了该方法的普遍适用性。我们表明,该方法在强耦合和化学等价机制中效率很高,并且可以克服其他成熟且更复杂脉冲序列的一些局限性。我们提供了一个模拟软件包,可用于确定脉冲序列参数。

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