Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan.
Chem Commun (Camb). 2019 Mar 21;55(25):3662-3665. doi: 10.1039/c9cc00829b.
The doped sites of locally functionalized single-walled carbon nanotubes emit red-shifted and bright near-infrared photoluminescence compared to non-doped nanotubes. Here, we observe unique photoluminescent solvatochromism. Organic solvent environments induce photoluminescent energy shifts that linearly correlate with a solvent polarity function. A high responsiveness at the doped sites is found.
与未掺杂的纳米管相比,局部功能化单壁碳纳米管的掺杂位点发出红移且明亮的近红外光致发光。在这里,我们观察到独特的光致发光溶剂变色现象。有机溶剂环境诱导光致发光能位移,与溶剂极性函数呈线性相关。在掺杂位点发现了高响应性。