Centre for Materials Science and Nanotechnology, Department of Chemistry, University of Oslo, P. O. Box 1033, N-0315 Oslo, Norway.
Chem Commun (Camb). 2019 Mar 26;55(26):3817-3820. doi: 10.1039/c9cc00920e.
The LiCl salt flux method is an established aid in oxyhydride synthesis. By operating the flux below its melting point, we have obtained phase pure Nd2LiHO3 for the first time. Further, the suitability of the flux method is shown to be dictated by a delicate balance between the thermal stability of the oxyhydride in question and the ionic mobility of the reactants.
LiCl 盐助熔剂法是一种成熟的氧氢化物合成辅助方法。通过在助熔剂熔点以下操作，我们首次获得了纯相的 Nd2LiHO3。此外，助熔剂法的适用性取决于所研究的氧氢化物的热稳定性和反应物的离子迁移率之间的微妙平衡。
