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通过琼脂凝胶铸造和固态烧结制备镧锶锰氧化物陶瓷

Fabrication of Lanthanum Strontium Manganite Ceramics via Agar Gel Casting and Solid State Sintering.

作者信息

Zhang Shiyu, Peng Cheng, Guan Chengzhi, Xiao Guoping, Wang Jianqiang

机构信息

Department of Molten Salt Chemistry and Engineering, and Key Laboratory of Interfacial Physics and Technology, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China.

University of Chinese Academy of Sciences, No.19(A) Yuquan Road, Shijingshan District, Beijing 100049, China.

出版信息

Materials (Basel). 2019 Mar 13;12(6):848. doi: 10.3390/ma12060848.

Abstract

Fabricating lanthanum strontium manganite (LSM) ceramics with certain shapes is important for the design and construction of high-temperature energy conversion and storage devices. Here, we describe a low-cost and environmentally friendly method for fabricating LSM ceramics via agar gel casting and high temperature sintering. This new approach uses temperature tuning to fabricate LSM gel bodies, not only by manufacturing in the secondary process but also by remolding and recycling during the gel casting process. The effect of the sintering temperature on the properties of LSM ceramics was investigated as well. As a result, the porosity and compressive strength of LSM ceramics sintered at 1000 °C are ~60% and 5.6 MPa, respectively. When the sintering temperature increases to 1200 °C, the porosity decreases to ~28%, whereas the compressive strength increases to 25 MPa, which is able to meet the requirement of cathode-supported SOFCs (solid oxide fuel cells).

摘要

制造具有特定形状的镧锶锰氧化物(LSM)陶瓷对于高温能量转换和存储设备的设计与构建至关重要。在此,我们描述了一种通过琼脂凝胶铸造和高温烧结来制造LSM陶瓷的低成本且环保的方法。这种新方法利用温度调节来制造LSM凝胶体,不仅通过二次加工制造,还通过在凝胶铸造过程中进行重塑和回收利用。同时研究了烧结温度对LSM陶瓷性能的影响。结果表明,在1000℃烧结的LSM陶瓷的孔隙率和抗压强度分别约为60%和5.6MPa。当烧结温度升至1200℃时,孔隙率降至约28%,而抗压强度增至25MPa,这能够满足阴极支撑型固体氧化物燃料电池(SOFC)的要求。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4df7/6472146/c31084cac3c4/materials-12-00848-g001.jpg

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