一种双三齿硝酰氮氧自由基及其金属配合物的合成与磁性质
Syntheses and magnetic properties of a bis-tridentate nitronyl nitroxide radical and its metal complexes.
作者信息
Miao Hao, Li Miao, Li Hong-Qing, Shen Fu-Xing, Zhang Yi-Quan, Wang Xin-Yi
机构信息
State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.
出版信息
Dalton Trans. 2019 Apr 9;48(15):4774-4778. doi: 10.1039/c9dt00207c.
PMID:30874271
Abstract
The first bis-tridentate nitronyl nitroxide mono-radical was synthesized. From this ligand and a bis-bidentate nitronyl nitroxide ligand, metal complexes of MnII and CoII ions were also synthesized and characterized. Field-induced slow magnetic relaxation was observed in the radical-bridged CoII complex.
摘要
首个双齿氮氧自由基单自由基被合成出来。基于该配体以及一个双二齿氮氧自由基配体，还合成并表征了锰（II）和钴（II）离子的金属配合物。在自由基桥连的钴（II）配合物中观察到了场诱导慢磁弛豫现象。
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