Instituto de Química, Centro Interdisciplinar de Energia e Ambiente (CIENAM), Instituto Nacional de Ciência e Tecnologia, INCT de Energia e Ambiente, Universidade Federal da Bahia, Rua Barão de Jeremoabo, s/n, Ondina, CEP 40170-290 Salvador, BA, Brazil.
Talanta. 2019 Jun 1;198:263-276. doi: 10.1016/j.talanta.2019.02.031. Epub 2019 Feb 6.
The present review reports, for the first time, various comprehensive two-dimensional gas chromatography (GC×GC) applications for different fossil fuel matrices (crude oil, heavy gas oil (HGO), light and middle distillates, coal and shale oil) for the determination of nitrogen-containing compounds. The focus is on the various types of detectors (universal and specific), and their applicability for the separation and speciation of nitrogen compounds (N-compounds) was evaluated. The capability of GC×GC to provide additional chemically specific information using different detector types, including a flame ionization detector (FID), a nitrogen chemiluminescence detector (NCD), a nitrogen-phosphorus (NPD) detector and detectors in combination with mass spectrometry (MS), is described. The coelutions (detection by MS) for various N-compounds, analytes and components of other classes, such as those that are oxygenates and hydrocarbons, are discussed.
本综述首次报道了各种综合二维气相色谱（GC×GC）在不同化石燃料基质（原油、重质瓦斯油（HGO）、轻质和中间馏分、煤和页岩油）中用于测定含氮化合物的应用。重点是各种类型的检测器（通用和专用），并评估了它们对氮化合物（N 化合物）分离和形态分析的适用性。描述了 GC×GC 使用不同类型的检测器（包括火焰离子化检测器（FID）、氮化学发光检测器（NCD）、氮磷（NPD）检测器和与质谱（MS）结合的检测器）提供额外化学特异性信息的能力。讨论了各种 N 化合物、其他类别的分析物和成分（如含氧化合物和烃类）的共洗脱（通过 MS 检测）。
