Salen-Co(iii) 在多变量阳离子金属有机骨架中的嵌入用于增强二氧化碳的环加成反应。
Salen-Co(iii) insertion in multivariate cationic metal-organic frameworks for the enhanced cycloaddition reaction of carbon dioxide.
机构信息
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fujian, Fuzhou, 350002, P. R. China.
出版信息
Chem Commun (Camb). 2019 Apr 2;55(28):4063-4066. doi: 10.1039/c8cc10268f.
PMID:30882802
Abstract
The salen-Co(iii) motif was inserted into imidazolium-functionalized multivariate cationic zirconium metal-organic frameworks (MOFs). The salen-Co(iii), as a Lewis acid site, and the Br- of imidazolium, as a nucleophile, are synergistically catalytic for the enhanced cycloaddition reaction of carbon dioxide with epoxides.
摘要
席夫碱钴(III)配合物被插入到咪唑功能化的多变量阳离子锆金属有机骨架（MOFs）中。席夫碱钴(III)作为路易斯酸位，而咪唑的 Br-作为亲核试剂，协同催化二氧化碳与环氧化物的增强环加成反应。
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