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磷灰石上的水。

Water on apatites.

作者信息

Misra D N

出版信息

Calcif Tissue Int. 1986 Jun;38(6):333-8. doi: 10.1007/BF02555746.

DOI:10.1007/BF02555746
PMID:3089555
Abstract

Adsorption of water was studied gravimetrically at 23 degrees C in an open system at several relative humidities on a variety of apatitic calcium phosphates including enamel, deproteinized enamel, and bone mineral. The amount of adsorbed water increases linearly with the surface areas of the synthetic apatites and does not appear very sensitive to calcium to phosphorus ratio of the apatites. The adsorption results correlate very well up to about two monolayers with a conventionally determined isotherm. Higher uptake of water even by "deproteinized" enamel or bone may be due to the presence of pore structure and incompletely removed organic matter.

摘要

在开放系统中,于23摄氏度下,在几种相对湿度条件下,采用重量法研究了水在多种磷灰石型磷酸钙(包括牙釉质、脱蛋白牙釉质和骨矿物质)上的吸附情况。吸附水的量随合成磷灰石的表面积呈线性增加,并且对磷灰石的钙磷比似乎不太敏感。在大约两个单分子层之前,吸附结果与传统测定的等温线非常吻合。即使是“脱蛋白”的牙釉质或骨骼对水的更高吸附量,可能是由于存在孔隙结构和未完全去除的有机物。

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引用本文的文献

1
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本文引用的文献

1
Hydrazine-deproteinated bone mineral. Physical and chemical properties.肼脱蛋白骨矿物质。物理和化学性质。
Calcif Tissue Res. 1973;12(1):73-90. doi: 10.1007/BF02013723.
2
Adsorption of water on tooth components and related materials.水在牙齿成分及相关材料上的吸附作用。
J Dent Res. 1973 Mar-Apr;52(2):271-80. doi: 10.1177/00220345730520021501.
3
Structural features of human dental enamel as revealed by isothermal water vapour sorption.等温水蒸气吸附揭示的人类牙釉质结构特征
Arch Oral Biol. 1975 May-Jun;20(5-6):317-25. doi: 10.1016/0003-9969(75)90021-7.
4
Vapor phase adsorption of water on hydroxyapatite.水在羟基磷灰石上的气相吸附
J Dent Res. 1977 Dec;56(12):1437-48. doi: 10.1177/00220345770560120101.
5
Thermodynamic solubility product of human tooth enamel: powdered sample.人牙釉质的热力学溶解度积:粉末样品
J Dent Res. 1975 Jul-Aug;54(4):728-36. doi: 10.1177/00220345750540040601.