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基于电矩和化学性质的加热油建模、表征及质量分析

Modelling, characterization and quality analysis of heated oil using electric moment and chemical properties.

作者信息

Rubalya Valantina S, Uma S, Jeya Prakash B G, Phebee Angeline D R, Alfred Maxwell A, Aravindhan R

机构信息

1Department of Physics, SASTRA Deemed University, Thirumalaisamudram, Thanjavur, Tamil Nadu 613401 India.

2Department of EIE, SASTRA Deemed University, Thirumalaisamudram, Thanjavur, Tamil Nadu 613401 India.

出版信息

J Food Sci Technol. 2019 Feb;56(2):571-579. doi: 10.1007/s13197-018-3511-5. Epub 2018 Dec 12.

Abstract

The effect of temperature (30-90 °C) on the electrical parameter: dielectric constant (ε) of Sunflower, Olive and Corn oil exposed to three cycles of heating to frying temperature (175 ± 5 °C) was studied to exhibit the quality analysis of oil. Dielectric constant of heated oil was measured using designed inter-digitated electrode capacitor at different frequency (10 kHz-5 MHz) and temperature (30-90 °C). Dielectric constant (ε) of oil samples increases with cycles of heating. Variation of dielectric constant with frequency was premeditated using quadratic equation and the dependency factor was observed to be R > 0.914. Chemical kinetic dielectric constant with temperature was studied using Arrhenius law and observed that activation energy increases with cycles of heating. Andrade's equation was also fitted with the variation of ε with temperature and the dependency factor (R between 0.978 to 0.999) was observed to be highly correlated. Experiential physical properties like density, refractive index and ε were significantly correlated with the pragmatic peroxide value. The observed relation between ε with chemical property divulges the suitability of measured dielectric constant in real time and continuous evaluation of edible oil quality analysis in food industry.

摘要

研究了温度(30 - 90°C)对向日葵油、橄榄油和玉米油电参数——介电常数(ε)的影响,这些油经历了三个加热至油炸温度(175 ± 5°C)的循环,以展示油的质量分析。使用设计的叉指电极电容器在不同频率(10 kHz - 5 MHz)和温度(30 - 90°C)下测量加热后油的介电常数。油样的介电常数(ε)随加热循环次数增加。使用二次方程预先考虑介电常数随频率的变化,观察到相关系数R > 0.914。使用阿伦尼乌斯定律研究化学动力学介电常数与温度的关系,观察到活化能随加热循环次数增加。安德拉德方程也拟合了ε随温度的变化,观察到相关系数(R在0.978至0.999之间)具有高度相关性。经验性物理性质如密度、折射率和ε与实际过氧化值显著相关。观察到的ε与化学性质之间的关系揭示了测量介电常数在食品工业中实时和连续评估食用油质量分析方面的适用性。

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