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氯化钠浓度对与硫代葡萄糖苷降解和红萝卜花青素稳定性相关的异味去除的影响。

Effect of sodium chloride concentration on off-flavor removal correlated to glucosinolate degradation and red radish anthocyanin stability.

作者信息

Chen Wentian, Karangwa Eric, Yu Jingyang, Xia Shuqin, Feng Biao, Zhang Xiaoming

机构信息

1State Key Laboratory of Food Science and Technology, School of Food Science and Technology, Jiangnan University, 1800 Lihu Road, Wuxi, 214122 Jiangsu People's Republic of China.

Research and Development, AAFUD Industry (Zhuhai) Co. Ltd, Zhuhai, 519085 Guangdong People's Republic of China.

出版信息

J Food Sci Technol. 2019 Feb;56(2):937-950. doi: 10.1007/s13197-018-03559-8. Epub 2019 Feb 5.

Abstract

Anthocyanin-rich concentrates from different red radish can be used as natural food colorants. However, the development of off-flavor during extraction has been major challenge in processing industries. This work aimed to evaluate the effect of sodium chloride (NaCl) concentration in phosphoric acidified medium pH 2.5 on removal of off-flavor from red radish anthocyanin. The effect of NaCl concentration on anthocyanin properties was also evaluated. Results showed that the total glucosinolate was highly degraded at high NaCl concentration (< 500 mM) compared with control, leading to higher off-flavor development. Additionally, the glucosinolate degradation was positively and significantly correlated to isothiocyanate, while was negatively and significantly correlated with dimethyl di-, trisulfide, cedrol, triacetin, 6-methyl-5-hepten-2-one. Moreover, total monomeric and color properties of extracted anthocyanins were degraded at high NaCl concentration (< 500 mM) compared with control. The tentative anthocyanin identification by UPLC-TQ-MS showed 12 glycosylated anthocyanins substituted at C3 and C5 in tested anthocyanin extracts. In conclusion, higher NaCl concentration (< 500 mM) could not be useful for red radish off-flavor removal and anthocyanin properties.

摘要

来自不同红萝卜的富含花青素的浓缩物可用作天然食用色素。然而,提取过程中异味的产生一直是加工行业的主要挑战。这项工作旨在评估磷酸酸化介质pH 2.5中氯化钠(NaCl)浓度对红萝卜花青素异味去除的影响。还评估了NaCl浓度对花青素性质的影响。结果表明,与对照相比,在高NaCl浓度(<500 mM)下总硫代葡萄糖苷高度降解,导致更高的异味产生。此外,硫代葡萄糖苷的降解与异硫氰酸酯呈正显著相关,而与二甲基二硫化物、三硫化物、雪松醇、三醋精、6-甲基-5-庚烯-2-酮呈负显著相关。此外,与对照相比,在高NaCl浓度(<500 mM)下提取的花青素的总单体和颜色性质会降解。通过UPLC-TQ-MS对花青素进行的初步鉴定显示,在所测试的花青素提取物中,有12种在C3和C5处被糖基化的花青素。总之,较高的NaCl浓度(<500 mM)对红萝卜异味去除和花青素性质并无益处。

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