Yuan Li Zhu, Wang Jia Ning, Ma Chun Yang, Guo Shu Hai
Institute of Ecology, Shandong Academy of Sciences, Jinan 250013, China; Institute of Applied Ecology, Chinese Academy of Sciences, Shen-yang 110016, China.
Institute of Ecology, Shandong Academy of Sciences, Jinan 250013, China.
Ying Yong Sheng Tai Xue Bao. 2019 Jan 20;30(1):10-20. doi: 10.13287/j.1001-9332.201901.003.
In China, fluoride pollution in soil is severe and poses a serious threat to human health and ecological security. However, how to control fluorine-contaminated soil has not received widespread attention. Here, we summarized fluorine speciation in soil and its main chemical reactions in water-soil system and reviewed the research progress on the remediation of fluorine-contaminated soils. Then, we proposed the focus of future research on fluorine-contaminated soil remediation. The aim of this review was providing the reference for the remediation of fluoride-contaminated soil. There are five forms of fluorine in soils, with the proportion of residual fluorine being over 90%. The reactions of fluorine in the soil solution mainly include precipitation-dissolution, complexation-dissociation, and adsorption-desorption. At present, the remediation technology of fluorine contaminated soil mainly focused on chemo-immobilization, chemical leaching, electrokinetic remediation, and phytoremediation. Clarifying the combined forms of fluorine in soil, screening functional microorga-nisms and plants, developing the combined remediation technology will be the focus of future research. Ultimately, on site fluorine-contaminated soil remediation could be implemented.
在中国,土壤中的氟污染严重,对人类健康和生态安全构成严重威胁。然而,如何治理氟污染土壤尚未受到广泛关注。在此,我们总结了土壤中氟的形态及其在水土系统中的主要化学反应,并综述了氟污染土壤修复的研究进展。然后,我们提出了未来氟污染土壤修复研究的重点。本综述旨在为氟污染土壤的修复提供参考。土壤中有五种氟形态,其中残留氟的比例超过90%。土壤溶液中氟的反应主要包括沉淀-溶解、络合-解离和吸附-解吸。目前,氟污染土壤的修复技术主要集中在化学固定、化学淋洗、电动修复和植物修复。明确土壤中氟的结合形态、筛选功能微生物和植物、开发联合修复技术将是未来研究的重点。最终,可以实施现场氟污染土壤修复。