Frei Angelo
Institute for Molecular Bioscience, The University of Queensland, St Lucia, Queensland, 4072, Australia.
Chemistry. 2019 May 23;25(29):7074-7090. doi: 10.1002/chem.201900276. Epub 2019 Apr 23.
Cyclopentadiene, and more importantly its functionalized derivatives, are a cornerstone of synthetic chemistry. Nowadays, they find applications in (chiral) catalysis, as ligands for organometallic complexes with potential diagnostic and therapeutic applications, and many more. This Minireview highlights the progress that has been made in the development of flexible and robust synthetic routes towards multifunctional cyclopentadienes in the last 20 years.
环戊二烯，更重要的是其功能化衍生物，是合成化学的基石。如今，它们在（手性）催化、作为具有潜在诊断和治疗应用的有机金属配合物的配体等方面有应用，还有更多其他应用。本综述重点介绍了过去20年中在开发通往多功能环戊二烯的灵活且稳健的合成路线方面所取得的进展。
