Liu Xin-Ran, Chen Xi-Meng, Zhang Jie, Jensen Torben R, Chen Xuenian
Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, China.
Dalton Trans. 2019 Apr 16;48(16):5140-5143. doi: 10.1039/c9dt00843h.
An efficient synthetic method for MB3H8 (M = Li and Na) has been developed with improved yields on the basis of the investigation of the interconversion between THF·B3H7 and corresponding MB3H8. The mechanism was tentatively proposed based on the understanding of the nucleophilicity of the B-H bonding pair electrons.
在对四氢呋喃·硼氢化三氢（THF·B₃H₇）与相应的MB₃H₈（M = Li和Na）之间的相互转化进行研究的基础上，已开发出一种高效合成MB₃H₈的方法，产率有所提高。基于对B - H键合电子对亲核性的理解，初步提出了反应机理。
