热老化对碳纤维增强环氧树脂层压板冲击和弯曲损伤行为的影响

Effect of Thermal Ageing on the Impact and Flexural Damage Behaviour of Carbon Fibre-Reinforced Epoxy Laminates.

作者信息

García-Moreno Irene, Caminero Miguel Ángel, Rodríguez Gloria Patricia, López-Cela Juan José

机构信息

Escuela Técnica Superior de Ingenieros Industriales, INEI, Universidad de Castilla-La Mancha, Campus Universitario s/n, 13071-Ciudad Real, Spain.

出版信息

Polymers (Basel). 2019 Jan 7;11(1):80. doi: 10.3390/polym11010080.

Abstract

Most of the composite materials that are used in aerospace structures have been manufactured using a thermostable matrix, as epoxy resin. The region of stability of these polymers is defined by the glass transition temperature (). However, operating temperatures close and above the can cause a variation in the properties of the polymer and consequently, modify the mechanical properties of the composite material. Therefore, it is necessary to understand the failure mechanisms that occur in the material in order to ensure stability and durability. The effect of temperature and time of exposure on the impact and flexural mechanical responses of carbon/epoxy composites are studied in this work. For that purpose, ageing treatments at temperatures below and above the have been considered and then, impact and flexural tests have been performed. It was observed that thermal ageing cause two different effects: at temperatures below the , there is an increase of the maximum strength because of a post-curing effect; however, the mechanical properties decrease at higher temperatures of thermal ageing due to the thermo-oxidation of the epoxy resin and the loss of adhesion in the matrix/fibre interface.

摘要

大多数用于航空航天结构的复合材料都是使用热稳定基体(如环氧树脂)制造的。这些聚合物的稳定区域由玻璃化转变温度()定义。然而,接近和高于该温度的工作温度会导致聚合物性能发生变化,进而改变复合材料的机械性能。因此,有必要了解材料中发生的失效机制,以确保其稳定性和耐久性。本工作研究了温度和暴露时间对碳/环氧复合材料冲击和弯曲力学响应的影响。为此,考虑了在低于和高于该温度的温度下进行老化处理,然后进行了冲击和弯曲试验。观察到热老化会产生两种不同的影响:在低于该温度时,由于后固化效应,最大强度会增加;然而,在较高的热老化温度下,由于环氧树脂的热氧化以及基体/纤维界面处附着力的丧失,机械性能会下降。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/04af/6402028/5e98e43118ac/polymers-11-00080-g001.jpg

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