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环境的化学和热影响对含环氧树脂碳复合材料力学性能降解的研究

The Study of Chemical and Thermal Influences of the Environment on the Degradation of Mechanical Properties of Carbon Composite with Epoxy Resin.

作者信息

Kojnoková Tatiana, Nový František, Markovičová Lenka

机构信息

Department of Materials Engineering, University of Žilina, 010 26 Žilina, Slovakia.

Research Centre, University of Žilina, 010 26 Žilina, Slovakia.

出版信息

Polymers (Basel). 2022 Aug 9;14(16):3245. doi: 10.3390/polym14163245.

Abstract

The present research deals with the investigation of the influence of aqueous solutions of chemical substances in combination with temperature on the change of material properties of polymer composites based on epoxy resins reinforced with carbon fibers. The aim of the research was to investigate and evaluate the impact of degradation processes due to the influence of chemical environments of different temperatures and time of their action on changes in the material properties and macrostructure of carbon composite with epoxy resin. The chemical and thermal influence of the environment on the experimental material was evaluated by monitoring changes in mechanical properties, glass transition temperature, and material surface macrostructure. The achieved results show different behavior of the experimental composite material in different environments, while it was demonstrated that the degradation effect of chemical and thermal influences on changes in material properties increase with increasing temperature. Among the investigated environments (NaCl, NaOH, and HSO), exposure to 10% NaOH, and 15% HSO had the greatest degradation influence on the polymer composite, and exposure to 20% NaCl had the smallest influence, which is also confirmed by invisible changes in material surface macrostructure and decrease of tensile strength by about 20%. Exposure to 10% NaOH resulted in significant surface roughening of the epoxy resin, white deposit creation on the surface, and a decrease of tensile strength by 35%. Opposite that, exposure to 15% HSO resulted in the highlighting of the fiber yarns of the carbon fiber fabric, yellowing of the surface, surface pore occurrence, and a decrease of tensile strength by 35%.

摘要

本研究探讨了化学物质水溶液与温度相结合对基于碳纤维增强环氧树脂的聚合物复合材料材料性能变化的影响。该研究的目的是调查和评估由于不同温度的化学环境及其作用时间的影响而导致的降解过程对含环氧树脂的碳复合材料的材料性能和宏观结构变化的影响。通过监测机械性能、玻璃化转变温度和材料表面宏观结构的变化来评估环境对实验材料的化学和热影响。所取得的结果表明,实验复合材料在不同环境中的行为不同,同时表明化学和热影响对材料性能变化的降解作用随温度升高而增加。在所研究的环境(氯化钠、氢氧化钠和硫酸)中,暴露于10%氢氧化钠和15%硫酸对聚合物复合材料的降解影响最大,而暴露于20%氯化钠的影响最小,这也通过材料表面宏观结构的不可见变化和拉伸强度降低约20%得到证实。暴露于10%氢氧化钠会导致环氧树脂表面显著粗糙化、表面出现白色沉积物以及拉伸强度降低35%。相反,暴露于15%硫酸会导致碳纤维织物的纤维纱突出、表面变黄、表面出现孔隙以及拉伸强度降低35%。

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