一种用于Sonogashira C-C交叉偶联反应的BODIPY功能化钯光氧化还原催化剂。
A BODIPY-functionalized Pd photoredox catalyst for Sonogashira C-C cross-coupling reactions.
作者信息
Dissanayake Komadhie C, Ebukuyo Peters O, Dhahir Yasser J, Wheeler Kraig, He Hongshan
机构信息
Department of Chemistry and Biochemistry, Eastern Illinois University, Charleston, IL 61920, USA.
出版信息
Chem Commun (Camb). 2019 Apr 23;55(34):4973-4976. doi: 10.1039/c9cc01365b.
PMID:30968098
Abstract
We report for the first time a BODIPY-functionalized dichloro(1,10-phenanthroline)palladium(ii) complex as an efficient photoredox catalyst for the Sonogashira C-C cross-coupling between phenylacetylene derivatives and iodobenzene derivatives with yields up to 92% under visible light illumination at room temperature.
摘要
我们首次报道了一种硼二吡咯功能化的二氯（1,10-菲咯啉）钯（II）配合物，它是一种高效的光氧化还原催化剂，用于苯乙炔衍生物与碘苯衍生物之间的Sonogashira C-C交叉偶联反应，在室温可见光照射下产率高达92%。
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