3D Organic-Inorganic Perovskite Ferroelastic Materials with Two Ferroelastic Phases: [Et P(CH ) F][Mn(dca) ] and [Et P(CH ) Cl][Mn(dca) ].

Organic-inorganic hybrid perovskite-type multiferroics have attracted considerable research interest owing to their fundamental scientific significance and promising technological applications in sensors and multiple-state memories. The recent achievements with divalent metal dicyanamide compounds revealed such malleable frameworks as a unique platform for developing novel functional materials. Herein, two 3D organic-inorganic hybrid perovskites [Et P(CH ) F][Mn(dca) ] (1) and [Et P(CH ) Cl][Mn(dca) ] (2) (dca=dicyanamide, N(CN) ) are presented. Accompanying the sequential phase transitions, they display a broad range of intriguing physical properties, including above room temperature ferroelastic behavior, switchable dielectricity, and low-temperature antiferromagnetic ordering (T =2.4 K for both 1 and 2). It is also worth noting that the spontaneous strain value of 1 is far beyond that of 2 in the first ferroelastic phase, as a result of the precise halogen substitution. From the point view of molecular design, this work should inspire further exploration of multifunctional molecular materials with desirable properties.