Photo-Induced Vertical Alignment of Liquid Crystals via In Situ Polymerization Initiated by Polyimide Containing Benzophenone.

Vertical alignment of liquid crystal (LC) was achieved in an easy and effective way: in situ photopolymerization of dodecyl acrylate (DA) monomers initiated by polyimide based on 3,3',4,4'-benzophenonetetracarboxylic dianhydride and 3,3'-dimethyl-4,4'-diaminodiphenyl methane (BTDA-DMMDA PI). The alignment behavior and alignment stabilities were characterized by a polarizing optical microscope (POM), which showed a stable vertical alignment after 12 h of thermal treatment. The chemical structures, morphology, and water contact angles of alignment films peeled from LC cells with and without DA monomers were analyzed by means of a Fourier transform infrared spectrometer (FTIR), a scanning electron microscope (SEM), and a contact angle tester, separately. The results confirmed that the DA monomers underwent self-polymerization and grafting polymerization initiated by the BTDA-DMMDA PI under ultraviolet irradiation, which aggregated on the surfaces of PI films. The water contact angles of the alignment films were about 15° higher, indicating a relative lower surface energy. In conclusion, the vertical alignment of LC was introduced by the low surface free energy of PI films grafted with DA polymer and intermolecular interactions between LC and DA polymers.