聚（3,3-二苄基-3,4-二氢-2H-噻吩并[3,4-b][1,4]二氧杂环庚烷）/铂复合薄膜作为染料敏化太阳能电池潜在的对电极

Poly(3,3-dibenzyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine)/Platinum Composite Films as Potential Counter Electrodes for Dye-Sensitized Solar Cells.

作者信息

Chou Jung-Chuan, Huang Yu-Chi, Wu Tzi-Yi, Liao Yi-Hung, Lai Chih-Hsien, Chu Chia-Ming, Lin Yu-Jen

机构信息

Graduate School of Electronic Engineering, National Yunlin University of Science and Technology, Yunlin 64002, Taiwan.

Department of Electronic Engineering, National Yunlin University of Science and Technology, Yunlin 64002, Taiwan.

出版信息

Polymers (Basel). 2017 Jul 7;9(7):271. doi: 10.3390/polym9070271.

DOI:10.3390/polym9070271

PMID:30970949

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6432400/

Abstract

In this study, poly(3,3-dibenzyl-3,4-dihydro-2-thieno[3,4-][1,4]dioxepine)/platinum composite films (PProDOT-Bz₂/Pt) were used as counter electrodes (CEs) in dye-sensitized solar cells (DSSCs). The composite films were prepared on fluorine-doped tin oxide (FTO) glass by radio frequency (RF) sputtering to deposit platinum (Pt) for 30 s. Afterwards, PProDOT-Bz₂ was deposited on the Pt⁻FTO glass via electrochemical polymerization. The electron transfer process of DSSCs was investigated using electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). The DSSCs with 0.05 C/cm² PProDOT-Bz₂-Pt composite films showed an open circuit voltage () of 0.70 V, a short-circuit current density () of 7.27 mA/cm², and a fill factor (F.F.) of 68.74%. This corresponded to a photovoltaic conversion efficiency (η) of 3.50% under a light intensity of 100 mW/cm².

摘要

在本研究中，聚（3,3-二苄基-3,4-二氢-2-噻吩并[3,4-][1,4]二氧杂环庚烷）/铂复合薄膜（PProDOT-Bz₂/Pt）被用作染料敏化太阳能电池（DSSC）的对电极（CE）。通过射频（RF）溅射在氟掺杂氧化锡（FTO）玻璃上制备复合薄膜，沉积铂（Pt）30秒。之后，通过电化学聚合将PProDOT-Bz₂沉积在Pt⁻FTO玻璃上。使用电化学阻抗谱（EIS）和循环伏安法（CV）研究了DSSC的电子转移过程。具有0.05 C/cm² PProDOT-Bz₂-Pt复合薄膜的DSSC的开路电压（）为0.70 V，短路电流密度（）为7.27 mA/cm²，填充因子（F.F.）为68.74%。这对应于在100 mW/cm²光强下3.50%的光伏转换效率（η）。