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利用来自巴伊亚腰果壳的活性炭从模拟医院废水中吸附去除阿莫西林。

Removal of amoxicillin from simulated hospital effluents by adsorption using activated carbons prepared from capsules of cashew of Para.

机构信息

Graduate program in Metallurgical, Mine and Materials Engineering (PPGE3M). School of Engineering, Federal University of Rio Grande do Sul (UFRGS), Av. Bento Gonçalves, Porto Alegre, RS, 9500, Brazil.

Institute of Chemistry, Federal University of Rio Grande do Sul (UFRGS), Av. Bento Gonçalves 9500, P.O. Box 15003, Porto Alegre, RS, 91501-970, Brazil.

出版信息

Environ Sci Pollut Res Int. 2019 Jun;26(16):16396-16408. doi: 10.1007/s11356-019-04994-6. Epub 2019 Apr 13.

Abstract

High-surface-area activated carbons were prepared from an agroindustrial residue, Bertholletia excelsa capsules known as capsules of Para cashew (CCP), that were utilized for removing amoxicillin from aqueous effluents. The activated carbons were prepared with the proportion of CCP:ZnCl 1:1, and this mixture was pyrolyzed at 600 (CCP-600) and 700 °C (CCP700). The CCP.600 and CCP.700 were characterized by CHN/O elemental analysis, the hydrophobic/hydrophilic ratio, FTIR, TGA, Boehm titration, total pore volume, and surface area. These analyses show that the adsorbents have different polar groups, which confers a hydrophilic surface. The adsorbents presented surface area and total pore volume of 1457 m g and 0.275 cm g (CCP.600) and 1419 m g and 0.285 cm g (CCP.700). The chemical and physical properties of the adsorbents were very close, indicating that the pyrolysis temperature of 600 and 700 °C does not bring relevant differences in the physical and chemical properties of these adsorbents. The adsorption data of kinetics and equilibrium were successfully adjusted to Avrami fractional-order and Liu isotherm model. The use of the adsorbents for treatment of simulated hospital effluents, containing different organic and inorganic compounds, showed excellent removals (up to 98.04% for CCP.600 and 98.60% CCP.700). Graphical abstract.

摘要

高比表面积活性炭由一种农业工业残渣——被称为腰果Para 坚果的胶囊(CCP)制备而成,用于从水溶液中去除阿莫西林。活性炭是用 CCP:ZnCl 1:1 的比例制备的,将该混合物在 600(CCP-600)和 700°C(CCP700)下进行热解。通过 CHN/O 元素分析、疏水性/亲水性比、FTIR、TGA、Boehm 滴定、总孔体积和表面积对 CCP.600 和 CCP.700 进行了表征。这些分析表明,吸附剂具有不同的极性基团,赋予其亲水性表面。吸附剂的比表面积和总孔体积分别为 1457 m2/g 和 0.275 cm3/g(CCP.600)和 1419 m2/g 和 0.285 cm3/g(CCP.700)。吸附剂的化学和物理性质非常接近,表明 600 和 700°C 的热解温度不会给这些吸附剂的物理和化学性质带来相关差异。动力学和平衡的吸附数据成功地调整为 Avrami 分数阶和 Liu 等温线模型。这些吸附剂用于处理含有不同有机和无机化合物的模拟医院废水时,表现出优异的去除率(CCP.600 可达 98.04%,CCP.700 可达 98.60%)。

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