通过主客体化学实现环肽-聚合物缀合物自组装的超分子开关。
Supramolecular switching of the self-assembly of cyclic peptide-polymer conjugates via host-guest chemistry.
机构信息
Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry CV4 7AL, UK.
出版信息
Chem Commun (Camb). 2019 May 8;55(36):5291-5294. doi: 10.1039/c9cc01914f. Epub 2019 Apr 17.
PMID:30994130
Abstract
A supramolecular strategy of switching the self-assembly of cyclic peptide-polymer conjugates using host-guest chemistry is proposed. The formation of tubular supramolecular polymers based on cyclic peptide-polymer conjugates can be controlled by reversibly attaching cucurbit[7]uril onto the cyclic peptide via host-guest interactions.
摘要
提出了一种利用主客体化学来切换环肽-聚合物缀合物自组装的超分子策略。通过主客体相互作用，将葫芦[7]脲可逆地连接到环肽上，可以控制基于环肽-聚合物缀合物的管状超分子聚合物的形成。
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