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基于聚合物稳定液晶的染料掺杂智能电致变色窗

Dye-Doped Electrically Smart Windows Based on Polymer-Stabilized Liquid Crystal.

作者信息

Sun Haitao, Xie Zuoping, Ju Chun, Hu Xiaowen, Yuan Dong, Zhao Wei, Shui Lingling, Zhou Guofu

机构信息

SCNU-TUE Joint Lab of Device Integrated Responsive Materials (DIRM), National Center for International Research on Green Optoelectronics, South China Normal University, No 378, West Waihuan Road, Guangzhou Higher Education Mega Center, Guangzhou 510006, China.

Guangdong Provincial Key Laboratory of Optical Information Materials and Technology & Institute of Electronic Paper Displays, South China Academy of Advanced Optoelectronics, South China Normal University, Guangzhou 510006, China.

出版信息

Polymers (Basel). 2019 Apr 16;11(4):694. doi: 10.3390/polym11040694.

Abstract

Here we report the fabrication of dye-doped polymer-stabilized liquid crystals (PSLC)-based smart windows. The effect of dye doping on PSLC contrast was investigated. Non-dichroic dye tints the PSLC sample in both off- and on-state, which is not beneficial for increasing its off/on contrast. The sample doped with dichroic dye shows a slight color in the off-state and strong color in the on-state, resulting in an enhanced contrast, which attributed to orientation dependent absorption of dichroic dyes. Furthermore, we blended non-dichroic dye and dichroic dye who have complementary absorption together into PSLC mixture. The sample is almost colorless in the off-state due to the subtractive process, while colored in the on-state. The contrast is further enhanced. The results show that the proposed multi-dye-doped PSLC device has high visual contrast and fast response time, making it attractive for applications in light management and architectural aesthetics.

摘要

在此,我们报告了基于染料掺杂聚合物稳定液晶(PSLC)的智能窗户的制备。研究了染料掺杂对PSLC对比度的影响。非二向色性染料在关态和开态下都会使PSLC样品着色,这不利于提高其关/开对比度。掺杂二向色性染料的样品在关态下呈现轻微颜色,在开态下呈现强烈颜色,从而导致对比度增强,这归因于二向色性染料的取向依赖性吸收。此外,我们将具有互补吸收的非二向色性染料和二向色性染料一起混入PSLC混合物中。由于减色过程,该样品在关态下几乎无色,而在开态下有颜色。对比度进一步提高。结果表明,所提出的多染料掺杂PSLC器件具有高视觉对比度和快速响应时间,使其在光管理和建筑美学应用中具有吸引力。

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