碘催化以磺酰氯为硫源无臭合成S-硫代氨基甲酸盐
Iodine-Catalyzed Odorless Synthesis of S-Thiocarbamates with Sulfonyl Chlorides as a Sulfur Source.
作者信息
Bao Wen-Hu, He Min, Wang Jing-Ting, Peng Xin, Sung Men, Tang Zilong, Jiang Si, Cao Zhong, He Wei-Min
机构信息
Department of Chemistry , Hunan University of Science and Engineering , Yongzhou 425100 , China.
School of Chemistry and Chemical Engineering , Hunan University of Science and Technology , Xiangtan 411201 , China.
出版信息
J Org Chem. 2019 May 17;84(10):6065-6071. doi: 10.1021/acs.joc.9b00178. Epub 2019 May 8.
PMID:30999750
Abstract
A general and efficient protocol for the direct preparation of various S-thiocarbamates with readily available and inexpensive sulfonyl chlorides as an odorless sulfur source was developed. The employment of easily available reactants, excellent functional group tolerability, and mild reaction conditions make this process very practical.
摘要
开发了一种通用且高效的方法，可直接制备各种S-硫代氨基甲酸盐，该方法使用容易获得且价格低廉的磺酰氯作为无臭硫源。使用易于获得的反应物、出色的官能团耐受性和温和的反应条件使该过程非常实用。
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