Novel TiO catalyst carriers with high thermostability for selective catalytic reduction of NO by NH.

A series of TiO catalyst carriers with ceria additives were prepared by a precipitation method and tested for selective catalytic reduction (SCR) of NO by NH. These samples were characterized by XRD, N-BET, NH-TPD, H-TPR, TEM, XPS and DRIFTS, respectively. Results showed that the appropriate addition of ceria can enhance the catalytic activity and thermostability of TiO catalyst carriers significantly. The maximum catalytic activity of Ti-Ce-O-500 is 98.5% at 400 °C with a GHSV of 100 000 h and the high catalytic activity still remains even after the treatment at high temperature for 24 h. The high catalytic performance of Ti-Ce-O-500 can be attributed to a series of superior properties, such as larger specific surface area, more Brønsted acid sites, more hydrogen consumption, and the higher proportion of chemisorbed oxygen. Ceria atoms can inhibit the crystalline grain growth and the collapse of small channels caused by high temperatures. Furthermore, DRIFTS in different feed gases show that the SCR reaction over Ti-Ce-O-500 follows both E-R and L-H mechanisms.