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AgNPs-TiO 数码涂层的光催化瓷质大板

Photocatalytic porcelain grés large slabs digitally coated with AgNPs-TiO.

机构信息

Dipartimento di Chimica, Università di Milano, Via Golgi 19, 20133, Milano, Italy.

Dipartimento di Chimica & NIS Interdept. Centre, Università di Torino, Via P. Giuria 7, 10125, Torino, Italy.

出版信息

Environ Sci Pollut Res Int. 2019 Dec;26(36):36117-36123. doi: 10.1007/s11356-019-05218-7. Epub 2019 Apr 25.

DOI:10.1007/s11356-019-05218-7
PMID:31020536
Abstract

TiO is employed as both photocatalytic and structural materials, leading to its applications in external coatings or in interior furnishing devices, including cement mortar, tiles, floorings, and glass supports. The authors have already demonstrated the efficiency of photoactive micro-sized TiO and here its industrial use is reported using the digital printing to coat porcelain grés slabs. Many advantages are immediately evident, namely rapid and precise deposition, no waste of raw materials, thus positively affecting the economy of the process. Data for the thin films deposited by digital printing were compared with those obtained for the conventional spray method. The use of metal-doped TiO is also reported so that the photoactivity of these materials can be exploited even under LED light. The digital inkjet printed coatings exhibited superior photocatalytic performance owing to both higher exposed surface area and greater volume of deposited anatase, as well as the greater areal distribution density of thinly and thickly coated regions. Moreover, the presence of TiO doped silver increased the efficiency of the materials in NOx degradation both under UVA and LED lights.

摘要

TiO 既可用作光催化材料,也可用作结构材料,因此可应用于外部涂层或内部装饰设备,包括水泥砂浆、瓷砖、地板和玻璃支架。作者已经证明了光活性微尺寸 TiO 的效率,这里报道了其使用数码打印在瓷质板岩上涂层的工业用途。许多优点是显而易见的,即快速、精确的沉积,没有原材料的浪费,从而对工艺的经济性产生积极影响。通过数码打印沉积的薄膜的数据与通过传统喷涂方法获得的数据进行了比较。还报告了金属掺杂 TiO 的使用情况,以便即使在 LED 光下也能利用这些材料的光活性。由于更高的暴露表面积和更大的沉积锐钛矿体积,以及更薄和更厚涂层区域的更大面积分布密度,喷墨打印涂层具有更好的光催化性能。此外,掺杂银的 TiO 的存在提高了材料在 UVA 和 LED 光下对氮氧化物降解的效率。

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