Reconfiguration of π-conjugated superstructures enabled by redox-assisted assembly.
作者信息
Liu Kaixuan, Mukhopadhyay Arindam, Ashcraft Adam, Liu Chuan, Levy Adam, Blackwelder Patricia, Olivier Jean-Hubert
机构信息
Department of Chemistry, University of Miami, Cox Science Center, 1301 Memorial Drive, Coral Gables, FL 33146, USA.
出版信息
Chem Commun (Camb). 2019 May 9;55(39):5603-5606. doi: 10.1039/c9cc01939a.
PMID:31020965
Abstract
We show that n-doping supramolecular assemblies built from perylene diimide units provides a means to modulate the structure-function properties of these materials. In addition to highlighting the design principles, a combination of spectroscopic and microscopic characterization correlates an increase in the free-exciton bandwidth with the formation of mesoscale hierarchical superstructures.
摘要
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