Schöne Sebastian, März Juliane, Stumpf Thorsten, Ikeda-Ohno Atsushi
Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Institute of Resource Ecology, Bautzner Landstraße 400, 01328 Dresden, Germany.
Dalton Trans. 2019 May 28;48(20):6700-6703. doi: 10.1039/c9dt01056d. Epub 2019 Apr 26.
Mixed-valent tri- and tetranuclear complexes of neptunium, [{NpCl}{NpOCl(THF)}]·THF and [{NpCl}{NpO(μ-Cl)(THF)}{μ-Cl}] (THF = tetrahydrofuran), were synthesised and characterised. Both the complexes are formed via the cation-cation interactions between the Np(iv) centre and the axial oxygens of the neptunyl(v) unit (i.e. trans-dioxo NpO cation), demonstrating the potential of cation-cation interactions for further exploring the oligomer/cluster chemistry of actinides.
合成并表征了镎的混合价态三核和四核配合物，即[{NpCl}{NpOCl(THF)}]·THF和[{NpCl}{NpO(μ-Cl)(THF)}{μ-Cl}]（THF = 四氢呋喃）。这两种配合物均通过Np(iv)中心与镎酰(v)单元的轴向氧原子（即反式二氧代NpO阳离子）之间的阳离子-阳离子相互作用形成，这表明阳离子-阳离子相互作用在进一步探索锕系元素的低聚物/簇化学方面具有潜力。
