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Ho改性Ce/TiO催化剂增强的低温NH-SCR性能

Enhanced low-temperature NH-SCR performance of Ce/TiO modified by Ho catalyst.

作者信息

Zhang Ting-Ting, Yan Li-Min

机构信息

Shanghai University Microelectronic R&D Center, Shanghai University, Shanghai 200072, People's Republic of China.

出版信息

R Soc Open Sci. 2019 Mar 13;6(3):182120. doi: 10.1098/rsos.182120. eCollection 2019 Mar.

Abstract

Holmium was used as a dopant to boost the low-temperature NH-selective catalytic reduction (SCR) performance of Ce/TiO catalyst. It was ascertained that certain amount of Ho-doping species could exceedingly improve the low-temperature SCR activity under 60 000 h of Ce/TiO, accompanied with the improvement of tolerance to HO and SO at 200°C. Characterization results manifested that Ho modification could not only result in inhibiting the growth of TiO crystals and the enlargement of specific surface area but also lead to the enhanced redox ability and the increased amount of surface-adsorbed substances, all of which could promote the low-temperature NH-SCR performance of Ce/TiO.

摘要

钬用作掺杂剂以提高Ce/TiO催化剂的低温NH选择性催化还原(SCR)性能。已确定,一定量的Ho掺杂物种可极大地提高Ce/TiO在60000小时下的低温SCR活性,并提高其在200°C时对HO和SO的耐受性。表征结果表明,Ho改性不仅可以抑制TiO晶体的生长和比表面积的增大,还可以提高氧化还原能力和表面吸附物质的量,所有这些都可以促进Ce/TiO的低温NH-SCR性能。

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