钴催化的不饱和二异丙基硅基醚的分子内硅基过氧化物反应。
Cobalt-Catalyzed Intramolecular Silylperoxidation of Unsaturated Diisopropylsilyl Ethers.
机构信息
Department of Chemistry , New York University , New York , New York 10003 , United States.
出版信息
J Org Chem. 2019 Jun 21;84(12):7564-7574. doi: 10.1021/acs.joc.9b00642. Epub 2019 May 30.
Abstract
A cobalt-catalyzed intramolecular silylperoxidation reaction was developed that allows for the conversion of unsaturated diisopropylsilyl ethers to 3-sila-1,2,4-trioxepanes. Reduction of the peroxide unit of the 3-sila-1,2,4-trioxepane yields six-membered ring diisopropylsilylene acetals.
摘要
发展了一种钴催化的分子内硅基过氧化物反应，该反应能够将不饱和二异丙基硅醚转化为 3-硅-1,2,4-三氧杂环戊烷。还原 3-硅-1,2,4-三氧杂环戊烷的过氧化物单元得到六元环二异丙基硅基亚乙烯基缩醛。
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