一种坚固的etb型金属有机框架，对丙酮和甲醇的共沸混合物表现出对丙酮的极性选择性吸附。
A robust etb-type metal-organic framework showing polarity-exclusive adsorption of acetone over methanol for their azeotropic mixture.
作者信息
Hu Han, Zhu Jiaxing, Yang Feilong, Chen Zhenxia, Deng Mingli, Weng Linhong, Ling Yun, Zhou Yaming
机构信息
Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai, 200438, China.
出版信息
Chem Commun (Camb). 2019 Jun 11;55(46):6495-6498. doi: 10.1039/c9cc02439e. Epub 2019 May 3.
We report a robust and rigid etb-type metal-organic framework, in which its pore surface is decorated with flexible ethoxyl groups. It shows unprecedentedly selective adsorption of acetone (E value of 0.355, kinetic diameter of 4.6 Å) over methanol (E value of 0.762, kinetic diameter of 3.6 Å) for their azeotropic mixture.
我们报道了一种坚固且刚性的etb型金属有机框架，其孔表面装饰有柔性乙氧基。对于丙酮（E值为0.355，动力学直径为4.6 Å）和甲醇（E值为0.762，动力学直径为3.6 Å）的共沸混合物，它表现出前所未有的对丙酮的选择性吸附。
Zotero 插件