Green intelligence environment school, Yangtze Normal University, Chongqing, 408100, China.
Chongqing Environmental Protection Center for Shale Gas Technology & Development, Fuling, Chongqing, 400800, China.
Environ Sci Pollut Res Int. 2019 Jun;26(17):17853-17857. doi: 10.1007/s11356-019-05273-0. Epub 2019 May 6.
The exploration and production of shale gas technology provides a way for utilization of clean fuels. However, during the exploration process of shale gas, enormous amount of drilling cutting was generated and had to be solidified and landfilled. So the accumulation of shale gas drilling cutting solidified body (SGDS)causes severe land resource misuse and environmental complications. This study focuses on the utilization of SGDS as a raw material for the production of cement clinker, and the phase composition, microstructure, and environmental performance of the cement clinker was investigated by X-ray powder diffraction (XRD), scanning electronic microscopy (SEM), energy-dispersive X-ray spectrum analysis (EDX), and soaking test, respectively. The results show that the cement clinker obtained mainly constitutes of typical Portland cement mineral (CS, CS, CA, and CAF). The leaching test indicated that the concentration of heavy metal ions in leachate is within the limits allowed by the state "Technical specification for co-processing of solid wastes in cement kiln" (GB 30760-2014). This study therefore provides a benchmark on environmental effects resulting from drilling cuttings and utilization of resources.
页岩气勘探开发技术为清洁能源的利用提供了途径。然而,在页岩气勘探过程中,会产生大量的钻井岩屑,这些岩屑必须进行固化和填埋。因此,页岩气钻井岩屑固化体(SGDS)的堆积造成了严重的土地资源浪费和环境问题。本研究以 SGDS 为原料生产水泥熟料为目标,采用 X 射线粉末衍射(XRD)、扫描电子显微镜(SEM)、能谱分析(EDX)和浸泡试验等手段,对水泥熟料的物相组成、微观结构和环境性能进行了研究。结果表明,所得水泥熟料主要由典型的波特兰水泥矿物(CS、CS、CA 和 CAF)组成。浸出试验表明,浸出液中重金属离子的浓度均低于《水泥窑协同处置固体废物污染控制标准》(GB 30760-2014)规定的限值。因此,本研究为钻井岩屑的环境影响和资源利用提供了基准。