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利用页岩气开采产生的油基泥浆钻屑废物生产水泥熟料。

Utilization of oil-based mud drilling cuttings wastes from shale gas extraction for cement clinker production.

机构信息

School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang, 621010, China.

State Key Laboratory of Environment-friendly Energy Materials, Southwest University of Science and Technology, Zhenyu Lai, No. 59, Qinglong Avenue Middle Section, Fucheng District, Mianyang City, 621010, Sichuan Province, China.

出版信息

Environ Sci Pollut Res Int. 2020 Sep;27(26):33075-33084. doi: 10.1007/s11356-020-09541-2. Epub 2020 Jun 11.

Abstract

A large amount of oil-based mud drilling cuttings (OBMDC) are generated during shale gas extraction, which adversely affects the environment. In order to realize the resource utilization of waste, the object of this paper is to study the feasibility of OBMDC to produce cement clinker. The results showed that at relatively low calcination temperature, adding a certain amount of OBMDC can produce cement clinker successfully and reduce fuel consumption. The compressive strength, hydration performance, and physical characteristics of clinker with 0, 3, 6, and 9% OBMDC were investigated by chemical analysis methods, X-ray diffraction, isothermal calorimetry, mercury intrusion, and energy dispersive spectroscopy. The results showed that the formulated cement has good hydration performance and the compressive strength also meets relevant standards. The heavy metal ions leaching test showed that the preparation of cement clinker by a low amount of OBMDC could effectively reduce the toxicity of OBMDC. In general, the preparation of cement clinker by OBMDC can realize the resource utilization of waste, effectively reduce its toxicity, and play a positive role in environmental protection.

摘要

在页岩气开采过程中会产生大量油基泥浆钻屑(OBMDC),这对环境造成了不利影响。为了实现废物资源化利用,本文旨在研究 OBMDC 生产水泥熟料的可行性。结果表明,在相对较低的煅烧温度下,添加一定量的 OBMDC 可以成功生产水泥熟料并降低燃料消耗。通过化学分析方法、X 射线衍射、等温量热法、压汞法和能谱分析,研究了添加 0、3、6 和 9%OBMDC 的熟料的抗压强度、水化性能和物理特性。结果表明,配制的水泥具有良好的水化性能,抗压强度也符合相关标准。重金属离子浸出试验表明,用少量 OBMDC 制备水泥熟料可以有效降低 OBMDC 的毒性。总的来说,用 OBMDC 制备水泥熟料可以实现废物的资源化利用,有效降低其毒性,对环境保护起到积极作用。

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