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采用高效液相色谱法测定噻唑啉酮除草剂在免耕水稻土中的淋溶潜能和残留活性。

Determination of the Leaching Potential and Residues Activity of Imidazolinone Herbicide in Clearfield Rice Soil Using High-Performance Liquid Chromatography.

机构信息

Faculty of Science, Institute of Biological Science, University of Malaya, 50603, Kuala Lumpur, Malaysia.

Department of Chemical Engineering, Faculty of Engineering, University of Malaya, 50603, Kuala Lumpur, Malaysia.

出版信息

Bull Environ Contam Toxicol. 2019 Aug;103(2):348-353. doi: 10.1007/s00128-019-02625-x. Epub 2019 May 8.

Abstract

The residual activity of herbicides may be detrimental to the environment, requiring analysis of the persistent residues in the soil and water. A field study was conducted to measure the residues of Imidazolinone (IMI) in three Clearfield® rice field soils at three different locations in Malaysia. The analyses of IMI in the soil samples were carried out using a high-performance liquid chromatography (HPLC). These herbicides are widely used; however, few studies have been conducted on both residues, especially in the context of Malaysian soil. Residues of imazapic and imazapyr were found to fall within 0.03-0.58 µg/mL and 0.03-1.96 µg/mL, respectively, in three locations. IMI herbicides are persistent in the soil, and their residues remain for up to 85 days after application. A pre-harvest study was suggested for these herbicides on water, which will provide a clearer indicator on the use of IMI in Clearfield® rice fields.

摘要

除草剂的残留活性可能对环境有害,需要对土壤和水中的持久性残留进行分析。在马来西亚的三个不同地点,进行了一项田间研究,以测量三种正大稻田间土壤中咪唑啉酮(IMI)的残留量。使用高效液相色谱法(HPLC)对土壤样品中的 IMI 进行了分析。这些除草剂被广泛使用,但对其残留量的研究很少,特别是在马来西亚土壤方面。在三个地点,发现咪草烟和咪草酯的残留量分别在 0.03-0.58μg/mL 和 0.03-1.96μg/mL 之间。IMI 除草剂在土壤中具有持久性,其残留量在施药后长达 85 天。建议对这些除草剂在水中进行收获前研究,这将为在正大稻田间使用 IMI 提供更清晰的指标。

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