Allylation of aldehydes by dual photoredox and nickel catalysis.
作者信息
Gualandi Andrea, Rodeghiero Giacomo, Faraone Adriana, Patuzzo Filippo, Marchini Marianna, Calogero Francesco, Perciaccante Rossana, Jansen Thomas Paul, Ceroni Paola, Cozzi Pier Giorgio
机构信息
Dipartimento di Chimica "G. Ciamician", ALMA MATER STUDIORUM Università di Bologna, Via Selmi 2, 40126 Bologna, Italy.
出版信息
Chem Commun (Camb). 2019 Jun 11;55(48):6838-6841. doi: 10.1039/c9cc03344k.
Here we report the application of dual nickel/photoredox catalysis to the allylation of aliphatic, aromatic and heteroaromatic aldehydes by using commercially available reagents. The process utilizes the combination of a Ni(ii) complex, [Ru(bpy)3]2+ as a photoredox catalyst, and allylacetate under blue LED irradiation, and allows the synthesis of a large variety of homoallylic alcohols.
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