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氯氧化铋纳米片组装体作为钾离子电池的新型负极材料

Bismuth oxychloride nanoflake assemblies as a new anode for potassium ion batteries.

作者信息

Li Wei, Xu Yang, Dong Yulian, Wu Yuhan, Zhang Chenglin, Zhou Min, Fu Qun, Wu Minghong, Lei Yong

机构信息

Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China.

出版信息

Chem Commun (Camb). 2019 Jun 4;55(46):6507-6510. doi: 10.1039/c9cc01937e.

DOI:10.1039/c9cc01937e
PMID:31099345
Abstract

This work reports the first demonstration of bismuth oxyhalides as anode materials in potassium-ion batteries. BiOCl nanoflake assemblies deliver high capacities of 367 mA h g-1 at 50 mA g-1 and 175 mA h g-1 at 1 A g-1. The formation of K-Bi alloys at an early stage of potassiation is observed.

摘要

这项工作报道了首次证明卤氧化铋作为钾离子电池负极材料的研究。BiOCl纳米片组装体在50 mA g-1电流密度下展现出367 mA h g-1的高容量,在1 A g-1电流密度下容量为175 mA h g-1。在钾化早期观察到了K-Bi合金的形成。

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引用本文的文献

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Advanced Bismuth-Based Anode Materials for Efficient Potassium Storage: Structural Features, Storage Mechanisms and Modification Strategies.用于高效钾存储的先进铋基负极材料:结构特征、存储机制及改性策略
Nanomicro Lett. 2025 Jan 31;17(1):126. doi: 10.1007/s40820-024-01641-9.
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Multipod Bi(CuS) Nanocrystals formed by Dynamic Cation-Ligand Complexation and Their Use as Anodes for Potassium-Ion Batteries.多足生物(CuS)纳米晶的动态阳离子-配体络合形成及其在钾离子电池中的应用。
Nano Lett. 2022 Dec 28;22(24):10120-10127. doi: 10.1021/acs.nanolett.2c03933. Epub 2022 Dec 6.
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Pyrrhotite Fe S microcubes as a new anode material in potassium-ion batteries.
磁黄铁矿FeS微立方体作为钾离子电池中的一种新型负极材料。
Microsyst Nanoeng. 2020 Sep 21;6:75. doi: 10.1038/s41378-020-00188-0. eCollection 2020.
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State-of-the-art anodes of potassium-ion batteries: synthesis, chemistry, and applications.钾离子电池的前沿阳极:合成、化学与应用
Chem Sci. 2021 May 11;12(22):7623-7655. doi: 10.1039/d0sc06894b.