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特制消失墨水与文件解密

Prepared Disappearing Ink and Deciphering of Documents.

作者信息

Asicioglu Faruk, Tekin Tugba, Ozbek Nil, Cevik Filiz Ekim, Ozcan Mustafa, Mohammed Linton A

机构信息

Department of Medicine, Institute of Forensic Sciences, Istanbul University-Cerrahpasa, Cerrahpasa, Istanbul, 34098, Turkey.

Department of Science, Institute of Forensic Sciences, Istanbul University-Cerrahpasa, Cerrahpasa, Istanbul, 34098, Turkey.

出版信息

J Forensic Sci. 2019 Nov;64(6):1898-1905. doi: 10.1111/1556-4029.14084. Epub 2019 May 31.

Abstract

Disappearing inks can be used for forgeries in many fields. In this study, thymolphthalein indicator solution was prepared as a disappearing ink. A total of 54 different solutions containing thymolphthalein were prepared at six different concentrations and nine different pH values. Among the prepared solutions, 0.16 g/50 mL and 0.32 g/65 mL thymolphthalein at pH 14 were the optimum solutions that were not distinguishable from regular ink when applied to promissory note. Fountain pens were filled with the abovementioned ink solutions and applied to promissory notes for experimental purposes. After 40 h, ink residues were not visible on promissory notes written with the ink with the optimum pH (pH = 14) value. To decipher the entries that disappeared, an instrumental method (Video Spectral Comparator-8000) and a chemical method (using NH vapor) were used, succeeded at 0.32 g/65 mL, but failed at 0.16 g/50 mL thymolphthalein. Therefore, NH had to be sprayed for 0.16 g/50 mL with negligible harm.

摘要

消色墨水可用于许多领域的伪造。在本研究中,制备了百里酚酞指示剂溶液作为消色墨水。以六种不同浓度和九种不同pH值制备了总共54种含有百里酚酞的不同溶液。在所制备的溶液中,pH值为14时,0.16 g/50 mL和0.32 g/65 mL的百里酚酞溶液是最佳溶液,应用于本票时与普通墨水无明显区别。用上述墨水溶液填充钢笔并应用于本票以进行实验。40小时后,用最佳pH值(pH = 14)的墨水书写的本票上看不到墨水残留。为了解读消失的字迹,使用了一种仪器方法(视频光谱比较仪-8000)和一种化学方法(使用氨气),在0.32 g/65 mL的百里酚酞溶液中成功,但在0.16 g/50 mL的百里酚酞溶液中失败。因此,对于0.16 g/50 mL的溶液,必须喷洒氨气,危害可忽略不计。

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