基于多金属氧酸盐的 CO 转化催化剂。
Polyoxometalate-Based Catalysts for CO Conversion.
机构信息
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, China.
University of Chinese Academy of Sciences, Beijing 100049, China.
出版信息
Molecules. 2019 May 30;24(11):2069. doi: 10.3390/molecules24112069.
Polyoxometalates (POMs) are a diverse class of anionic metal-oxo clusters with intriguing chemical and physical properties. Owing to unrivaled versatility and structural variation, POMs have been extensively utilized for catalysis for a plethora of reactions. In this focused review, the applications of POMs as promising catalysts or co-catalysts for CO conversion, including CO photo/electro reduction and CO as a carbonyl source for the carbonylation process are summarized. A brief perspective on the potentiality in this field is proposed.
多金属氧酸盐（POMs）是一类具有有趣化学和物理性质的阴离子金属氧簇，具有广泛的应用。由于其无与伦比的多功能性和结构变化，POMs 已被广泛用于多种反应的催化。在这篇重点综述中，总结了 POMs 作为 CO 转化的有前途的催化剂或共催化剂的应用，包括 CO 的光/电还原以及 CO 作为羰基化过程的羰基源。对该领域的潜力提出了简要的看法。
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