单、双和三簇间键：对MAu(SR)（M = Au、Pd、Pt）作为14、12和10价超原子分子的分析。
Single, double, and triple intercluster bonds: analyses of MAu(SR) (M = Au, Pd, Pt) as 14-, 12- and 10-ve superatomic molecules.
作者信息
Muñoz-Castro Alvaro
机构信息
Instituto de Ciencias Químicas Aplicadas, Grupo de Química Inorgánica y Materiales Moleculares, Facultad de Ingeniería, Universidad Autonoma de Chile, Av. El Llano Subercaseaux 2801, San Miguel, Santiago de Chile.
出版信息
Chem Commun (Camb). 2019 Jun 20;55(51):7307-7310. doi: 10.1039/c9cc02970b.
The bonding picture of the experimentally characterized species derived from the M2Au36(SR)24 cluster is discussed to indicate the occurrence of the classical notion of single, double and triple chemical bonds. The bond order can be reversibly controlled by tuning their charge states which is shown to be opportunely extended to clusters in favor of the conception of molecularly structured materials.
讨论了从M2Au36(SR)24团簇衍生出的经实验表征的物种的键合情况，以表明单键、双键和三键等经典化学键概念的存在。键级可以通过调节它们的电荷状态进行可逆控制，这表明可以适当地扩展到团簇，以支持分子结构材料的概念。
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