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橡胶籽油/亚麻籽油共混醇酸树脂:理化性质的比较研究

Alkyd resin from rubber seed oil/linseed oil blend: A comparative study of the physiochemical properties.

作者信息

Otabor G O, Ifijen I H, Mohammed F U, Aigbodion A I, Ikhuoria E U

机构信息

Department of Chemistry, University of Benin, Benin City, Nigeria.

Product Development Laboratory, Rubber Research Institute of Nigeria, P. M. B., 1049, Benin City, Nigeria.

出版信息

Heliyon. 2019 May 7;5(5):e01621. doi: 10.1016/j.heliyon.2019.e01621. eCollection 2019 May.

Abstract

This study was aimed at the synthesis and characterization of alkyd from rubber seed/linseed oil blends. Different percentages of rubber seed oil were blended with linseed oil for the preparation of alkyd via condensation polymerisation of monoglyceride with phthalic anhydride. Physiochemical properties like colour, acid value, saponification value, iodine value, drying schedule, chemical resistance were evaluated for the different alkyd samples synthesized. The colour of the different samples was unaffected by blending. The acid values of the alkyds obtained were observed to be in the range of 8.59-10.1 mgKOH/g. The iodine values of the different alkyd samples prepared increased with increase in the percentage of linseed oil in the blends. The blends showed resistance to brine, water and acid. However, only some exhibited fair resistance to alkali. The intrinsic viscosity was also determined by extrapolation from Huggins and Kraemer viscosity relationship. The results showed that the alkyd resins synthesized from the blend of linseed and rubber seed oil showed favourable properties that make linseed oil good blending oil for the synthesis of alkyd resin.

摘要

本研究旨在合成并表征由橡胶籽油/亚麻籽油共混物制成的醇酸树脂。将不同比例的橡胶籽油与亚麻籽油混合,通过甘油单酯与邻苯二甲酸酐的缩聚反应制备醇酸树脂。对合成的不同醇酸树脂样品的物理化学性质进行了评估,包括颜色、酸值、皂化值、碘值、干燥时间表、耐化学性等。不同样品的颜色不受混合的影响。所获得的醇酸树脂的酸值在8.59 - 10.1 mgKOH/g范围内。制备的不同醇酸树脂样品的碘值随着共混物中亚麻籽油比例的增加而增加。这些共混物表现出对盐水、水和酸的耐受性。然而,只有一些对碱表现出中等耐受性。还通过从哈金斯和克雷默粘度关系进行外推来测定特性粘度。结果表明,由亚麻籽和橡胶籽油共混物合成的醇酸树脂表现出良好的性能,这使得亚麻籽油成为合成醇酸树脂的优良混合油。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/94b1/6512889/1c9fa9b4915e/sc1.jpg

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