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由生物基资源生产的醇酸树脂，用于更具可持续性和环境友好型的涂料应用。

Alkyd resins produced from bio-based resources for more sustainable and environmentally friendly coating applications.

作者信息

Dizman Cemil, Cerrahoğlu Kaçakgil Elif

机构信息

İzel Kimya Research and Development Center, Dilovası, Kocaeli, Turkey.

出版信息

Turk J Chem. 2022 Oct 8;47(1):1-23. doi: 10.55730/1300-0527.3511. eCollection 2023.

DOI:10.55730/1300-0527.3511
PMID:37731964
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10507036/
Abstract

Recently, due to the depletion of natural resources and raising environmental and economic concerns regarding petroleum derivatives, the creation of novel ecologically friendly and sustainable materials made from bio-based and renewable resources is gaining popularity. Alkyd resins are synthetic resins in which both renewable (fatty acids, glycerol, oil, etc.) and nonrenewable (maleic anhydride, pentaerythritol, phthalic anhydride, etc.) raw materials are used in their production. Due to their superior performance (good aging, greater weather resistance and high heat resistance, outstanding gloss, etc.) over other resins, easy application, low cost, and varied use, in the coating and paint industries, they are commonly used. This review covers the studies on bio-based monomers used instead of nonrenewable ones in the production of alkyds. The effects of substituted bio-based monomers on the final properties (adhesiveness, drying times, hardness, tackiness, etc.) of produced alkyds and coatings are also discussed in detail.

摘要

近年来，由于自然资源的枯竭以及对石油衍生物环境和经济问题的日益关注，利用生物基和可再生资源制造新型生态友好型和可持续材料越来越受到欢迎。醇酸树脂是一种合成树脂，其生产过程中使用了可再生（脂肪酸、甘油、油等）和不可再生（马来酸酐、季戊四醇、邻苯二甲酸酐等）原料。由于其性能优于其他树脂（良好的老化性能、更强的耐候性和高耐热性、出色的光泽等）、易于应用、成本低且用途广泛，在涂料和油漆行业中被广泛使用。本综述涵盖了在醇酸树脂生产中使用生物基单体替代不可再生单体的研究。还详细讨论了取代生物基单体对所生产醇酸树脂和涂料最终性能（附着力、干燥时间、硬度、粘性等）的影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbd3/10507036/d7b63664f60b/turkjchem-47-1-1f11.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbd3/10507036/d7b63664f60b/turkjchem-47-1-1f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbd3/10507036/2ff363fd18dc/turkjchem-47-1-1f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbd3/10507036/0734ce9ae983/turkjchem-47-1-1f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbd3/10507036/b28017c57bcf/turkjchem-47-1-1f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbd3/10507036/a0fedf022a09/turkjchem-47-1-1f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbd3/10507036/584439d1dd22/turkjchem-47-1-1f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbd3/10507036/165ce4841615/turkjchem-47-1-1f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbd3/10507036/9a04178b15cd/turkjchem-47-1-1f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbd3/10507036/2bae40578a16/turkjchem-47-1-1f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbd3/10507036/4760f3d7f2bb/turkjchem-47-1-1f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbd3/10507036/a4cc927d7e0e/turkjchem-47-1-1f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bbd3/10507036/d7b63664f60b/turkjchem-47-1-1f11.jpg

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