Ashraf Sobia, Siddiqa Asima, Shahida Shabnam, Qaisar Sara
Department of Chemistry, University of Poonch Rawalakot, Azad Kashmir, India.
NanoScience and Technology Department, National Centre for Physics, Islamabad, Pakistan.
Heliyon. 2019 May 15;5(5):e01577. doi: 10.1016/j.heliyon.2019.e01577. eCollection 2019 May.
Arsenic is highly carcinogenic element and less concentration of this chemical element makes natural water unsafe for human consumption. Versatile techniques including adsorption method have been established to remove the arsenic from water. However, adsorption is found to be one of effective method for the remediation of arsenic from contaminated water. Different types of natural adsorbents i.e. clays, waste materials, carbon based material have been studied widely for the adsorption of arsenic. Recently, nanotechnology is considered to be one of the best technology for waste water treatment. Therefore researchers have synthesized several types of nanoadsorbents and investigated them for the removal of various pollutants including arsenic from water. Now days, attention is paid on development of nanocomposite materials which are proven as competent arsenic adsorbent candidate as compared to other adsorbents due to dominant structural and surface features. Various metal/metal oxide based nanocomposites have been developed and studied for arsenic removal from aqueous media. It has been reported that TiO based nanocomposite exhibit stong affinity for both inorganic form of arsenic. Therefore, in this review numerous metal or metal oxide based titania nanocomposites i.e. TiO-αFeO, NHITO, Ce-Ti oxide, Zr-TiO RGO-MFT etc. have been discussed in details for the water treatment containing arsenic. This review also presents an overview of low cost adsorbents, titania based nanoadsorbent and hybrid titania nanostructures for the removal of arsenic. In this review paper the particle size, surface area and adsorption efficiency of these titania based materials at different pH are also been presented in tabulated form. It provides the opportunity to choose best titania based nanocomposites for the treatment of arsenic polluted water.
砷是一种高致癌性元素,这种化学元素浓度较低就会使天然水不适于人类饮用。包括吸附法在内的多种技术已被用于从水中去除砷。然而,吸附被认为是从受污染水中去除砷的有效方法之一。不同类型的天然吸附剂,如粘土、废料、碳基材料等,已被广泛研究用于吸附砷。最近,纳米技术被认为是废水处理的最佳技术之一。因此,研究人员合成了几种类型的纳米吸附剂,并研究了它们对包括水中砷在内的各种污染物的去除效果。如今,人们关注纳米复合材料的开发,由于其主要的结构和表面特性,与其他吸附剂相比,纳米复合材料被证明是有竞争力的砷吸附剂候选材料。各种基于金属/金属氧化物的纳米复合材料已被开发并用于从水介质中去除砷。据报道,基于TiO的纳米复合材料对无机形态的砷都具有很强的亲和力。因此,在本综述中,详细讨论了多种基于金属或金属氧化物的二氧化钛纳米复合材料,如TiO-αFeO、NHITO、Ce-Ti氧化物、Zr-TiO、RGO-MFT等,用于含砷水处理。本综述还概述了用于去除砷的低成本吸附剂、基于二氧化钛的纳米吸附剂和混合二氧化钛纳米结构。在这篇综述论文中,还以表格形式列出了这些基于二氧化钛的材料在不同pH值下的粒径、表面积和吸附效率。这为选择最佳的基于二氧化钛的纳米复合材料处理砷污染水提供了机会。